BRQZQ - PETROBOND II

Product Identification

Product ID:PETROBOND II
MSDS Date:02/01/1992
FSC:5610
NIIN:00N042906
MSDS Number: BRQZQ

Responsible Party
BAROID DRILLING FLUIDS INC
HOUSTON, TX 77251
US

Emergency Phone: 713-987-4000

Info Phone: 713-987-5900

Cage: HO821

Contractor
BAROID DRILLING FLUIDS,INC.
1675 HOUSTON, TX 77251 US

Telephone: 713-987-4000/713-987-5900

Cage: 20064

Ingredients

SILICA, CRYSTALLINE - QUARTZ; (SILICA)

CAS: 14808-60-7

RTECS: VV7330000

Fraction By Weight: 2-6%

OSHA PEL SEE TABLE Z3

ACGIH TLV: 0.1 MG/M3 RDUST;9293

Hazards

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:THIS PRODUCT CONTAINS FREE CRYSTALLINE
SILICA WHICH ACCORDING TO IARC HAS EXHIBITED LIMITED EVIDENCE OF
CARCINOGENICITY IN HUMANS. PROLONGED INHALATION OF POWDER MAY
RESULT IN SILICOSIS, A NONCANCEROU S LUNG DISEASE. EYES:MAY CAUSE
IRRITATION. SKIN: POTENTIAL IRRITANT. INGEST:ACCIDENTAL INGESTION
OF (EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE - QUARTZ:IARC
MONOGRAPHS, SUPP, VOL 7, PG 341, 1987:GRP 2A. NTP 6TH ANNUAL RPT ON
CARCINS, (SUPDAT)
Effects of Overexposure:HLTH HAZ:SMALL QUANTITIES IS NOT EXPECTED TO
HAVE DAMAGING HEALTH EFFECTS. INHAL:DUST MAY BE IRRITATING TO
LUNGS, NOSE & THROAT; PROLONGED INHALATION MAY CAUSE LUNG INJURY OR
DISEASE.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid

First Aid:EYES:WASH W/WATER FOR AT LEAST 15 MINUTES. IF IRRITATION
CONTINUES, GET MEDICAL ATTENTION. SKIN:WASH THOROUGHLY W/SOAP &
WATER. IF IRRITATION CONTINUES, GET MEDICAL ATTENTION. INGEST:IF
LARGE QUANTITI ES ARE INGESTED DO NOT INDUCE VOMITING.DRINK 2
GLASSES OF WATER & GET MEDICAL ATTENTION. INHAL:REMOVE VICTIM TO
FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN.

Fire Fighting

Extinguishing Media:WATER.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:MAY GIVE OFF TOXIC VAPORS WHEN BURNED.

Accidental Release

Spill Release Procedures:NORMAL HOUSEKEEPING; SWEEP UP & PLACE IN
DISPOSAL CONTAINER.

Handling

Handling and Storage Precautions:STORE IN A SHELTERED AREA OR COVER TO
PROTECT FROM MOISTURE.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Exposure Controls

Respiratory Protection:IF DUSTY CONDITIONS, USE NIOSH/MSHA APPROVED
RESPIRATOR FOR NONTOXIC DUSTS.
Ventilation:MECHANICAL GENERAL ROOM VENTILATION. USE LOCAL VENTILATION
TO MAINTAIN TLV.
Protective Gloves:BUTYL RUBBER GLOVES.
Eye Protection:CHEMICAL SAFETY GOGGLES .
Other Protective Equipment:APRON, COVERALLS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLAN OF CARCIN:1991:ANTICIPATED TO BE A CARCINOGEN.

Chemical Properties

HCC:T6
Spec Gravity:2-2.3 (H2O=1)
Appearance and Odor:RED POWDER.

Stability

Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BURNING MAY RELEASE CARBON DIOXIDE,
CARBON MONOXIDE.

Disposal

Waste Disposal Methods:DISPOSE OF I/A/W ALL LOCAL, STATE & FEDERAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.